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A proposal has been made to study the properties of an atom composed of a π+(mπ+ = 237.2me) and a µ-(mµ- = 206.77me) in order to measure the charge radius of the pion. Assume that all of the pion charge is spread uniformly on a spherical shell at R0 = 10-13 cm and that the µ is a point charge. Express the potential as a Coulomb potential for a point charge plus a perturbation and use perturbation theory to calculate a numerical value for the percentage shift in the 1s -2p energy difference A. Neglect spin orbit effects and Lamb shift. Given

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The Coulomb potential energy of the muon is

It can be written in the form

is to be treated as a perturbation.

The energy levels and wave functions of the unperturbed system are

As spin orbit and Lamb effects are to be neglected, we need only consider Rnl in perturbation calculations. Thus

Thus a0 >> R and the factor exp(-2r/a0) in the integrand above may be neglected. Hence

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