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+1 vote
1.4k views
in Chemistry by (48.9k points)

Statement 1 : S8 disproportionate into H2S2O3 and S2- in alkaline medium

Statement 2 : ClO\(^-_4\) undergoes disproportionation in acidic medium. 

(1) Statement 1 is correct but statement 2 is incorrect 

(2) Statement 1 is incorrect but statement 2 is correct 

(3) Both statement 1 and statement 2 are correct 

(4) Both statement 1 and statement 2 are incorrect

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1 Answer

+1 vote
by (47.7k points)

(1) Statement 1 is correct but statement 2 is incorrect 

S8 disproportionate into H2S2O3 and S2- in alkaline medium

(2) Cl is in its highest oxidation state (+7). It cannot be further oxidised.

Therefore, statement 1 is correct but statement 2 is incorrect.

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