S2O42-, S2O82-
In H2S, +2 +x = 0; x = -2
In H2SO4, +2 +x - 8 = 0; x = +6
In S2O42-, 2x - 8 = -2; 2x = 6, x = +
In S2O42-, let one of S = x, than 2x + 4(-8) = -2 ∴ x = +3
In S2O82- there is peroxide linkage, therefore oxidation state of 'S' is 6 because