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in Chemistry by (49.7k points)

What is meant by the following terms? Give an example of the reaction in each case. 

1. Cyanohydrin 

2. Acetal 

3. Semicarbazone 

4. Aldol 

5. Hemiacetal 

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1. Cyanohydrin: Compounds possessing hydroxyl and cyano groups on the same carbon atom, ie. gem-hydroxy nitrates are called cyanohydrin. These are produced by addition of HCN to aldehydes or ketones in weakly basic medium.

2. Acetal: Compounds in which the two alkoxy groups are present on the terminal carbon atom are called acetals. These are produced by the action of an aldehyde with two equivalents of a mono hydric alcohol in presence of dry HCl gas.

3. Semicarbazone: These are derivatives of aldehydes and ketones, and are produced by action of semicarbazide on them in weakly acidic medium.

4. Aldol: Aldols are β- hydroxy aldehydes and are produced by the condensation of two molecules of the same or one molecule each of two different aldehydes in presence of a dilute aqueous base such as NaOH, KOH, Ba(OH)2 etc For eg:

5. Hemiacetal: They are gem-alkoxy alcohol. These are produced by addition of one molecule of a monohydric alcohol to an aldehyde in presence of dry HCl gas.

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