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Calculate the pressure exerted by 8.5 g of NH3 contained in a 0.5 L vessel at 300 K. For ammonia a = 4.0 atm L2 mol-2 and b = 0.036 L mol-1 

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V =0.5 L , T = 300 K 

 n= 8.5/17 = 0.5 mol 

 ( P + an2 /V2 ) (V – nb) = nRT 

 Putting values , we have 

 P = 21.51 atm

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