1. In certain solvent, solute molecules associate to form a dimer. This reduces the total number of molecules formed in solution and as a result the calculated molar mass will be higher than the actual molar mass.
2. Acetic acid in benzene exist as a dimer

3. The molar mass of acetic acid calculate using colligative properties is found to be around 120 g mol-1 is two times of the actual molar mass 60 g mol-1.