1. The electrolyte NaCI dissociates completely into its constituent ions in their aqueous solution. This causes an increase in the total number olparticles present in the solution.
2. When we dissolve 1 mole of NaCI in water it. dissociates and gives 1 mole of Na+ and 1 mole of Cl- . Hence the solution will have 2 moles of particles.
But when we dissolve 1 mole of urea (non electrolyte) in water it appears as 1 mole only. So the colligative property value would be double in NaCl than in urea.